Triaquachlorido(1,10-phenanthroline-κ2N,N′)cobalt(II) chloride monohydrate
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چکیده
منابع مشابه
Triaquachlorido(1,10-phenanthroline-κ2 N,N′)cobalt(II) chloride monohydrate
In the title compound, [CoCl(C(12)H(8)N(2))(H(2)O)(3)]Cl·H(2)O, the Co(II) ion is coordinated by two N atoms from the 1,10-phenanthroline ligand [Co-N = 2.125 (6) and 2.146 (6) Å], one chloride ligand [Co-Cl = 2.459 (2)Å] and three water mol-ecules [Co-O = 2.070 (5)-2.105 (5)Å] in a distorted octa-hedral geometry. Inter-molecular O-H⋯Cl and O-H⋯O hydrogen bonds form an extensive three-dimension...
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In the title hydrated molecular salt, C(9)H(9)N(2) (+)·Cl(-)·H(2)O, the dihedral angle between the five- and six-membered rings in the cation is 18.00 (2)°. O-H⋯Cl, N-H⋯O and N-H⋯Cl hrdrogen-bonding inter-actions are present in the crystal structure.
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The crystal structure of the title salt, C(8)H(12)N(+)·Cl(-)·H(2)O, consists of discrete organic cations, chloride anions and water mol-ecules which are connected by N-H⋯Cl, N-H⋯O and O-H⋯Cl hydrogen bonds. These inter-actions lead to the formation of layers lying parallel to the ab plane.
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In the title salt, C(19)H(23)N(2)O(+)·Cl(-)·H(2)O, the ions and the water mol-ecule are held together by O-H⋯Cl, N-H⋯Cl, O-H⋯O, O-H⋯N and C-H⋯Cl hydrogen bonds, forming a three-dimensional framework. The vinyl group is disordered over two orientations with refined occupancies of 0.564 (16) and 0.436 (16). The cell parameters of the title compound have been reported previously [Griffiths (1952 ▶...
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In the title hydrated mol-ecular salt, C(8)H(12)N(+)·Cl(-)·H(2)O, the component species inter-act by way of N-H⋯O, N-H⋯Cl and O-H⋯Cl hydrogen bonds, resulting in a three-dimensional network.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2008
ISSN: 1600-5368
DOI: 10.1107/s1600536808042591